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Plastics & Resins
Cytec manufactures both "reactive" and "additive" type phosphorus containing compounds for flame retardant polymers and plastics. CYAGARD® RF 1243 and CYAGARD RF 1241 flame retardant containing two reactive hydroxyl functional groups are ideal fro epoxy and poly urethane applications. Inert compounds such as CYAGARD RF 67 and CYAGARD RF 1204 are useful for imparting flame retardancy to poly propylene and rayon. Such compounds offer an alternative to brominated flame retardants.
Higher molecular weight CYPHOS® phosphonium salts as well as certain high molecular weight tertiary phosphine oxides are useful anti-stats for polycarbonates and other polymeric materials. The latter may also be used as plasticizers.
The high thermal stability of phosphonium salts makes them useful for modified clays used to impart special properties such as high impact strength and gas impermeability to synthetic polymers.
Both BPD and BPOD have found selective use in the flame retardant and additives sector. BPD, when reacted with acrylic acid, leads to a non-halogenated flame retardant for use with polyester fabric. BPOD has been under investigation as a monomer in polymeric flame retardants. As additives, BPOD is added to polyurethane formulations as a polymerization control agent in foundry resin applications. BPD is hydrolyzed to benzene phosphonous acid (BPA), an additive in nylon 6,6 manufacture.
| Plastics & Resins Product Information |
| Product Name |
Chemical Name |
Format |
| CYAGARD 1241 flame retardant |
bis (hydroxymethyl) isobutylphosphine oxide |
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| CYAGARD 1243 flame retardant |
bis (3-hydroxypropyl) isobutylphosphine oxide |
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| TOPO |
trioctylphosphine oxide |
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| TTBPT |
tetradecyl(tributyl)phosphonium tosylate |
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| BPD |
benzene phosphorus dichloride |
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| BPOD |
benzene phosphorus oxydichloride |
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| Plastics/Resins Technical References |
| Category |
Journal |
Title |
Author |
| Anti-stats |
US 4943380, Takemoto Yushi Kabushiki Kaisha |
Antistatic Resin Composition with Transparency Containing Phosphonium Sulphonate |
Masato Sugiura; Hideo Shimizu; Shigeru Imamura; Fumitoshi Kaisha |
| US 5,973,102; General Electric Company |
Static Resistant Polycarbonate Compositions |
McCloskey, P.; Dardaris, G.; Knight, C. and Nye, A |
| Epoxy cure |
WO 2003072655, Hitachi Chemical Co., Ltd., Japan |
Encapsulating epoxy resin composition, and electronic parts device using the same |
Ikezawa, Ryoichi; Akimoto, Takayuki; Takahashi, Yoshihiro; Katayose, Mitsuo; Watanabe, Naoki; Nakamura, Shinya |
| Plastics/Polymers |
Polymer (2003), 44, 7291-7298 |
Synthesis, characterization and polymerization of isobutylbis(glycidylpropylether)phosphine oxide |
Alcon, M.J.; Ribera, G.; Galia, M. and Cadiz, V |
| Nanocomposites |
Chem. Matet., (2002),14,4837-4845 |
Thermal stability of quaternary phosphonium modified Montmorillonites |
Xie, W; Xie, R; Pan, W; Hunter, D; Koene, B; Tan, L and Vaia, R |
| WO/200078540; Triton Systems, Inc. |
High perfommance nanoparticles |
Singh, A and Koene, B; |
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