Phosphine & Phosphorus Specialties
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Cytec - Flame Retardants - Cytec manufactures both "reactive" and "additive" phosphorus derivatives containing compounds for flame retardant polymers and plastics. CYAGARD® RF 1243 and CYAGARD RF 1241, CYAGARD RF 67, CYAGARD RF 1204, CYPHOS phosphonium salts, TOPO, TTBPT, BPD, BPODFlame Retardants


Cytec manufactures both "reactive" and "additive" phosphorus derivatives containing compounds for flame retardant polymers and plastics. CYAGARD® RF 1243 and CYAGARD RF 1241 flame retardant containing two reactive hydroxyl functional groups are ideal for epoxy and polyurethane applications. Inert compounds such as CYAGARD RF 67 and CYAGARD RF 1204 are useful for imparting flame retardancy to polypropylene and rayon. Such compounds offer an alternative to brominated flame retardants.

Higher molecular weight CYPHOS® phosphonium salts as well as certain high molecular weight tertiary phosphine oxides are useful anti-stats for polycarbonates and other polymeric materials. The latter may also be used as plasticizers.

The high thermal stability of phosphonium salts makes them useful for modified clays used to impart special properties such as high impact strength and gas impermeability to synthetic polymers.

Both BPD and BPOD have found selective use in the flame retardant and additives sector. BPD when reacted with acrylic acid leads to a non-halogenated flame retardant for use with polyester fabric. BPOD has been under investigation as a monomer in polymeric flame retardants. As additives, BPOD is added to polyurethane formulations as a polymerization control agent in foundry resin applications. BPD is hydrolyzed to benzene phosphonous acid (BPA), an additive in nylon 6,6 manufacture.

Flame Retardants/Plastic Additives Product Information
Product Name Chemical Name Format
CYAGARD 1241 RF flame retardant bis-(hydroxymethyl) isobutylphosphine oxide  
CYAGARD 1243 RF flame retardant bis-(3-hydroxypropyl) isobutylphosphine oxide  
TOPO trioctylphosphine oxide  
TTBPT tetradecyl(tributyl)phosphonium tosylate  
BPD benzene phosphorus dichloride Download PDF
BPOD benzene phosphorus oxydichloride Download PDF

Flame Retardants/Plastic Additives Technical References
Category Journal Title Author
Plastics/Polymers

Polymer (2003), 44, 7291-7298 Synthesis, characterization and polymerization of isobutylbis(glycidylpropylether)phosphine oxide Alcon, M.J.; Ribera, G.; Galia, M. and Cadiz, V
Textiles US 3725001,United States Dept. of Agriculture Phosphinidynetrimethanol triacetate Lanoux, Sigred B.; Ellzey, Samuel E., Jr.; Drake, George L., Jr.; Reeves,Wilson A.
US 3846155, Hooker Chemicals and Plastics Corp., USA
Durable flameproofing of cellulosic materials
Wagner, George M.
GB 1519017, American Cyanamid Co., USA Flame-resistant textiles Longfield, James E.; Nakajima, William N.
US 4044055, American Cyanamid Co., USA
Tetrakis(hydroxymethyl)phosphonium salts Katz, Daniel Stanley
US 6130327, Lenzing AG
Regenerated Cellulose Incorporating Phosphorus Compounds so as to be Flame-Retardant Rainer Wolf; Hartmut Ruf
 
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